周瑶,王龙祥,方惠明

• 1:中国煤炭地质总局勘查研究总院
• 2:矿山透明地质与数字孪生技术国家矿山安监局重点实验室
• 3:河北中色华冠岩土工程有限公司

摘要(Abstract)：

水泥基注浆材料作为岩土工程与地下工程领域的关键材料，其性能优化与技术创新对提升注浆加固效果、推动绿色低碳发展具有重要意义。本文系统综述了我国水泥基注浆材料的研究进展，围绕材料研制、扩散性能与加固性能三个核心方向，梳理了近年来在配浆方法优化、外加剂功能化设计及工业固废协同利用等方面的研究成果。研究表明，通过响应面法、正交试验等实验设计方法，结合纳米材料、功能聚合物及固废掺合料的应用，显著提升了浆液的抗水分散性、析水稳定性及结石体强度；基于黏度时变模型、渗滤效应理论及数值模拟技术，逐步揭示了复杂介质中浆液扩散的时空演化规律；在加固性能研究中，机器学习算法的引入为注浆体强度预测与环境适应性分析提供了新思路。然而，现有研究仍面临微观作用机制不清晰、极端环境长期耐久性不足、智能化调控技术滞后等挑战。未来研究需聚焦绿色环保型材料的开发（如碱激发胶凝体系）、多尺度性能关联机制的揭示，以及人工智能技术的应用，推动水泥基注浆材料向“高性能化、低碳化、智能化”方向跨越发展，为复杂地质条件下的工程实践提供理论支撑与技术保障。

关键词(KeyWords)： 水泥基注浆材料;外加剂;配浆方法;扩散性能;加固性能;环境适应性;绿色低碳

Abstract:

Keywords:

基金项目(Foundation): 矿山透明地质与数字孪生技术国家矿山安全监察局重点实验室青年创新基金项目;; 中国煤炭地质总局勘查研究总院青年科技创新基金项目（ZYQJ-2024-5）

作者(Author): 周瑶,王龙祥,方惠明

参考文献(References)：

• [1]刘红彬：唐伟奇，肖凯璐，等.水泥基注浆材料的研究进展[J].混凝土，2016(3):71-75.LIU H, TANG W, XIAO K, et al.Research progress of cement-based grouting materials[J].Concrete, 2016(3):71-75.
• [2]DA R G,F S L, SáNCHEZ L,et al. A comprehensive review of cementitious grouts:Composition, properties, requirements and advanced performance[J]. Construction and Building Materials,2023(375):1-16.
• [3]杜明瑞.碳纳米管增强水泥基注浆材料力学特性及其微观作用机理[D].江苏徐州：中国矿业大学，2018.DU M. Mechanical properties of the carbon nanotubes enhanced cement-based grout and the microscopic mechanism[D]. Xuzhou,Jiangsu:China University of Mining and Technology,2018.
• [4]付宏渊，付思妮，邱祥，等.纳米Al2O3协同水性环氧树脂对水泥基锚固注浆材料改性研究[J].硅酸盐通报，2022,41(9):3016-3027.FU H, FU S, QIU X, et al. Modification of cement-based anchoring grouting material by Nano-Al2O3 synergistic with waterborne epoxy resin[J]. Bulletin of the Chinese Ceramic Society,2022,41(9):3016-3027.
• [5]宋国壮，王连俊，张艳荣，等.聚合物-水泥基注浆材料早期流变及水化特性[J].哈尔滨工业大学学报，2018,50(9):31-35.SONG G, WANG L, ZHANG Y, et al. Rheological and hydration properties of polymer-cementitious grouting material at early stage[J].Journal of Harbin Institute of Technology,2018,50(9):31-35.
• [6]李鑫磊，韩晓龙，李永利，等.VAE改性水泥基注浆材料性能研究[J].矿业研究与开发，2021,41(9):108-112.LI X, HAN X, LI Y, et al. Properties and application of VAE modified cement-based grouting material[J]. Mining Research and Development,2021,41(9):108-112.
• [7]张健.赤泥协同多源固废制备注浆材料组成设计、水化机理与性能调控[D].山东济南：山东大学，2021.ZHANG J. Composition design, hydration mechanism and performance control of grouting material prepared by red mud and multi-source solid waste[D]. Ji’nan,Shandong:Shandong University, 2021.
• [8]李召峰，高益凡，张健，等.水溶性植物胶改性水泥–水玻璃封堵材料试验研究[J].岩土工程学报，2020,42(7):1312-1321.LI Z, GAO Y, ZHANG J, et al. Experimental study of water-soluble vegetable gum-modified cement-sodium silicate plugging materials[J].Chinese Journal of Geotechnical Engineering, 2020,42(7):1312-1321.
• [9]冯啸，刘人太，李术才，等.考虑深层渗滤效应的水泥浆动界面特征研究[J].岩石力学与工程学报，2016,35(5):1000-1008.FENG X, LIU R, LI S, et al. Characteristics of moving interface of grout considering deep bed filtration[J]. Chinese Journal of Rock Mechanics and Engineering, 2016,35(5):1000-1008.
• [10]刘健，刘人太，张霄，等.水泥浆液裂隙注浆扩散规律模型试验与数值模拟[J].岩石力学与工程学报，2012,31(12):2445-2452.LIU J, LIU R, ZHANG X, et al. Diffusion law model test and numberical simulation of cement fracture grouting[J]. Chinese Journal of Rock Mechanics and Engineering,2012,31(12):2445-2452.
• [11]徐潇航，胡张莉，刘加平，等.基于机器学习回归模型的三峡大坝混凝土强度预测[J].材料导报，2023,37(2):45-53.XU X, HU Z, LIU J, et al. Concrete strength prediction of the three gorges dam based on machine learning regression model[J]. Materials Reports,2023,37(2):45-53.
• [12]张玉.水泥基注浆材料浆液扩散规律和预测控制试验研究[D].北京：北京交通大学，2020.ZHANG Y. Experimental research on law and prediction-control of slurry diffusion using cement-based grouting material[D]. Beijing:Beijing Jiaotong University, 2020.
• [13]赵青，张艺霞，赵军，等.速凝抗水分散型水泥基注浆材料的制备及性能研究[J].功能材料，2020,51(6):6114-6119,6157.ZHAO Q, ZHANG Y, ZHAO J, et al. Study on the preparation and performance of cement-based grouting material with quick setting and water resistance[J]. Journal of Functional Materials, 2020,51(6):6114-6119,6157.
• [14]张文宏，刘映晶，王军棋，等.基于硅灰对注浆材料抗水分散性能影响的外加剂优化研究[J].现代隧道技术，2022,59(4):265-272,283.ZHANG W, LIU Y, WANG J, et al. Study on the optimization of admixtures based on the impact of silica fume on the water dispersion resistance of grouting materials[J]. Modern Tunnelling Technology,2022,59(4):265-272,283.
• [15]耿大新，胡宇琛，廖煜祺，等.基于响应面法的泥水盾构同步注浆材料性能[J].科学技术与工程，2021,21(15):6479-6486.GENG D, HU Y, LIAO Y, et al. Performance of synchronous grouting material for slurry shield based on response surface method[J]. Science Technology and Engineering,2021,21(15):6479-6486.
• [16]吴爱祥，于少峰，韩斌，等.超细水泥注浆溶液配比优化及扩散规律研究[J].采矿与安全工程学报，2014,31(2):304-309.WU A, YU S, HAN B, et al. Optimization of mix-proportion and diffusing rule of super-fine cement grouting slurry[J]. Journal of Mining&Safety Engineering,2014,31(2):304-309.
• [17]胡意志.新型水泥基复合注浆材料的配比实验[J].矿业研究与开发，2017,37(3):44-46.HU Y. Proportion experiments of new cement-based composite grouting material[J]. Mining Research and Development,2017,37(3):44-46.
• [18]阮文军，王文臣，胡安兵.新型水泥复合浆液的研制及其应用[J].岩土工程学报，2001(2):212-216.RUAN W, WANG W, HU A. Development and application of new kind of cement composite grout[J]. Chinese Journal of Geotechnical Engineering,2001(2):212-216.
• [19]梁龙，张鑫，刘巧玲.浆体流变性能对超高延性水泥基材料性能的影响[J].材料导报，2023,37(5):101-107.LIANG L, ZHANG X, LIU Q. Effect of rheology on properties of ultrahigh ductility cementitious composites[J]. Materials Reports,2021,37(5):101-17.
• [20]程马遥，曾洋，杨虹.碳纳米管增强水泥基注浆材料的制备及其注浆性能研究[J].功能材料，2020,51(11):11207-11213.CHENG M, ZENG Y, YANG H. Preparation and grouting properties of carbonnanotubes reinforced cement-based grouting materials[J].Journal of Functional Materials,2020,51(11):11207-11213.
• [21]胡涛，万志辉，戴国亮，等.饱和土中后注浆灌注桩的注浆压力回归分析及优化[J].东南大学学报（自然科学版），2022,52(5):875-882.HU T, WAN Z, DAI G, et al. Regression analysis and optimization for grouting pressure of post-grouting pile in saturated soil[J]. Journal of Southeast University(Natural Science Edition),2022,52(5):875-882.
• [22]魏婧.碳纳米管改性水泥基注浆材料的制备及性能研究[J].功能材料，2022,53(8):8180-8185.WEI J. Preparation and properties of cement-based grouting materials modified by carbon nanotubes[J]. Journal of Functional Materials,2022,53(8):8180-8185.
• [23]刘铸.纤维-聚合物复合增强水泥基注浆材料配合比试验研究[D].湖南湘潭：湖南科技大学，2019.LIU Z. Experimental study on mix ratio of fiberpolymer composite cement-based grouting materials[D]. Xiangtan,Hunan:Hunan University of Science and Technology,2019.
• [24]刘盼.纤维增强聚合物改性水泥基注浆材料试验及应用研究[D].湖南长沙：长沙理工大学，2017.LIU P. The experiment and applied research on fiber reinforced and polymer modified cement based grouting material[D]. Changsha,Hunan:Changsha University of Science and Technology, 2017.
• [25]周璇.超高性能注浆纤维水泥基材料性能研究[D].湖南长沙：湖南大学，2017.ZHOU X. Research of performance of ultra high performance-slurry infiltrated fiber cementitious composites[D].Changsha,Hunan:Hunan University, 2017.
• [26]范利丹，孙亮，余永强，等.偏高岭土提高水泥基注浆材料在高地温隧道工程中的适应性[J].材料导报，2022,36(6):105-112.FAN L, SUN L, YU Y, et al. Metakaolin improves adaptability of cement-based grouting materials used in high geotemperature tunnel engineering[J]. Materials Reports,2022,36(6):105-112.
• [27]张欢.外加剂对水泥基注浆材料流变性能的调控作用[D].上海：华东理工大学，2014.ZHANG H. Regulation of admixtures on the rheological behavior of cemetitous grout[D]. Shanghai:East China University of Science and Technology, 2014.
• [28]程思嫄，陈代果，古巍.氧化石墨烯改性水泥基注浆材料的制备及力学性能研究[J].功能材料，2023,54(2):2153-2158.CHEN S, CHEN D, GU W. Preparation and mechanical properties of graphene oxide modified cement-based grouting materials[J]. Journal of Functional Materials,2023,54(2):2153-2158.
• [29]童立元，潘石，邱钰，等.大掺量粉煤灰注浆充填材料试验研究[J].东南大学学报（自然科学版），2002(4):643-647.TONG L, PAN S, Q, et al. Experimental research on grouting material with large volume fly ash[J]. Journal of Southeast University(Natural Science Edition),2002(4):643-647.
• [30]邹友平，张华兴，张刚艳，等.粉煤灰水泥注浆材料主要性能试验研究[J].煤矿开采，2012,17(4):15-16,95.QIU Y, ZHANG H, ZHANG G,et al. Main properties test of flyashcement grout material[J]. Coal Mining Technology,2012,17(4):15-16,95.
• [31]李标，马芹永，张发.超细矿渣粉与硅灰对水泥基注浆材料性能影响机理分析[J].硅酸盐通报，2022,41(12):4342-4352.LI B, MA Q, ZHANG F. Influence mechanism analysis of ultrafine ground granulated blast furnace slag and silica fume on properties of cement-based grouting material[J]. Bulletin of the Chinese Ceramic Society,2022,41(12):4342-4352.
• [32]谷天峰，孙忠弟，骆凤涛，等.水泥-黄土注浆充填材料的试验研究[J].工程地质学报，2014,22(1):98-105.GU T, SUN Z, LUO F, et al. Experimental research on loess grouting material for coal gob filling[J]. Journal of Engineering Geology,2014,22(1):98-105.
• [33]巫茂寅，王起才，张戎令，等.复合水泥基-水玻璃双液注浆材料胶凝性能及抗压强度试验研究[J].硅酸盐通报，2016,35(9):2741-2746.WU M, WANG Q, ZHANG R, et al. Cementing performance and compressive strength of complex cementitions-sodium silicate two-shot grouting materials[J]. Bulletin of the Chinese Ceramic Society,2016,35(9):2741-2746.
• [34]豆海军.复合水泥基-水玻璃双液注浆材料性能及微观特性研究[D].北京：中国地质大学（北京），2014.DOU H. Investigation on the performance and microscopic characteristics of complex cementitious-sodium silicate two-shot grouting materials[D]. Beijing:China University of Geosciences(Beijing), 2014.
• [35]李术才，韩伟伟，张庆松，等.地下工程动水注浆速凝浆液黏度时变特性研究[J].岩石力学与工程学报，2013,32(1):1-7.LI S, HAN W, ZHANG Q, et al. Research on time-dependent behavior of viscosity of fast curing grouts in underground construction grouting[J]. Chinese Journal of Rock Mechanics and Engineering,2013,32(1):1-7.
• [36]李术才，刘人太，张庆松，等.基于黏度时变性的水泥–玻璃浆液扩散机制研究[J].岩石力学与工程学报，2013,32(12):2415-2421.LI S, LIU R, ZHANG Q, et al. Research on C-S slurry diffusion mechanism with time-dependent behavior of viscosity[J]. Chinese Journal of Rock Mechanics and Engineering,2013,32(12):2415-2421.
• [37]李术才，郑卓，刘人太，等.基于渗滤效应的多孔介质渗透注浆扩散规律分析[J].岩石力学与工程学报，2015,34(12):2401-2409.LI S, ZHENG Z, LIU R, et al. Analysis of diffusion of grout in porous media considering infiltration effects[J]. Chinese Journal of Rock Mechanics and Engineering,2015,34(12):2401-2409.
• [38]杨志全，侯克鹏，郭婷婷，等.基于考虑时变性的宾汉姆流体的渗透注浆机理研究[J].四川大学学报（工程科学版），2011,43(S1):67-72.YANG Z, HOU K, GUO T, et al. Study on penetration grouting mechanism based on Bingham fluid of time-dependent behavior[J].Journal of Sichuan University(Engineering Science Edition),2011,43(S1):67-72.
• [39]杨志全，牛向东，侯克鹏，等.流变参数时变性幂律型水泥浆液的柱形渗透注浆机制研究[J].岩石力学与工程学报，2015,34(7):1415-1425.YANG Z, NIU X, HOU K, et al. Columnar diffusion of cement grout with time dependent rheological parameters[J]. Chinese Journal of Rock Mechanics and Engineering,2015, 34(7):1415-1425.
• [40]杨志全，侯克鹏，梁维，等.牛顿流体柱-半球面渗透注浆形式扩散参数的研究[J].岩土力学，2014,35(S2):17-24.YANG Z, HOU K, LIANG W, et al. Study of diffusion parameters of Newtonian fluid based on column-hemispherical penetration grouting[J]. Rock and Soil Mechanics,2014,35(S2):17-24.
• [41]杨志全，侯克鹏，程涌，等.幂律型流体的柱-半球形渗透注浆机制研究[J].岩石力学与工程学报，2014,33(S2):3840-3846.YANG Z, HOU K, CHENG Y, et al. Study of column-hemispherical penetration grouting mechanism based on power-law fluid[J]. Chinese Journal of Rock Mechanics and Engineering, 2014,33(S2):3840-3846.
• [42]李相辉，张庆松，张霄，等.水泥浆析水性能试验研究[J].建筑材料学报，2018,21(1):8-14.LI X, ZHANG Q, ZHANG X, et al. Research on water-bleeding property of cement slurry[J]. Journal of Building materials,2018,21(1):8-14.
• [43]徐斌，董书宁，徐路路，等.水泥基注浆材料浆液稳定性及其析水规律试验[J].煤田地质与勘探，2019,47(5):24-31.XU B, DONG S, ZHANG X, et al. Stability of cement-based grouting slurry and test of its bleeding law[J]. Coal Geology and Exploration,2019,47(5):24-31.
• [44]张润畦，徐斌，尹尚先，等.水泥基注浆材料析水时变特性量化试验研究[J].煤田地质与勘探，2022,50(11):153-161.ZHANG R, XU B, YIN S, et al. Quantitative experimental study on time-varying characteristics of bleeding of cement-based grouting materials[J]. Coal Geology and Exploration,2022,50(11):153-161.
• [45]王晓晨，刘人太，杨为民，等.考虑水泥浆液析水作用的水平裂隙注浆扩散机制研究[J].岩石力学与工程学报，2019,38(5):1005-1017.WANG X, LIU R, YANG W, et al. Study on grouting mechanism of horizontal fractures considering the bleeding of cement slurry[J].Chinese Journal of Rock Mechanics and Engineering,2019,38(5):1005-1017.
• [46]孙锋，张顶立，陈铁林.基于流体时变性的隧道劈裂注浆机理研究[J].岩土工程学报，2011,33(1):88-93.SUN F, ZHANG D, CHEN T, et al. Fracture grouting mechanism in tunnels based on time-dependent behaviors of grout[J]. Chinese Journal of Geotechnical Engineering,2011,33(1):88-93.
• [47]张连震，张庆松，刘人太，等.考虑浆液黏度时空变化的速凝浆液渗透注浆扩散机制研究[J].岩土力学，2017,38(2):443-452.ZHANG L, ZHANG Q, LIU R, et al. Penetration grouting mechanism of quick setting slurry considering spatiotemporal variation of viscosity[J]. Rock and Soil Mechanics,2017,38(2):443-452.
• [48]李术才，冯啸，刘人太，等.考虑渗滤效应的砂土介质注浆扩散规律研究[J].岩土力学，2017,38(4):925-933.LI S, FENG X, LIU R, et al. Diffusion of grouting cement in sandy soil considering filtration effect[J]. Rock and Soil Mechanics,2017,38(4):925-933.
• [49]房凯，夏唐代，包柳青，等.考虑滤过效应的卵砾石层浆液扩散研究[J].岩石力学与工程学报，2013,32(7):1443-1448.FANG K, XIA T, BAO L, et al. Cement grout dispersion considering filtration in gravel[J]. Chinese Journal of Rock Mechanics and Engineering,2013,32(7):1443-1448.
• [50]张玉.水泥基注浆材料浆液扩散规律和预测控制试验研究[D].北京：北京交通大学，2020.ZHANG Y. Experimental research on law and prediction-control of slurry diffusion using cement-based grouting material[D]. Beijing:Beijing Jiaotong University, 2020.
• [51]阮文军.注浆扩散与浆液若干基本性能研究[J].岩土工程学报，2005(1):69-73.RUAN W. Research on diffusion of grouting and basic properties of grouts[J]. Chinese Journal of Geotechnical Engineering,2005(1):69-73.
• [52]阮文军.基于浆液粘度时变性的岩体裂隙注浆扩散模型[J].岩石力学与工程学报，2005(15):2709-2714.RUAN W. Spreading model of grouting in rock mass fissures based on time-dependent behavior of viscosity of cement-based grouts[J].Chinese Journal of Rock Mechanics and Engineering, 2005(15):2709-2714.
• [53]刘人太，张连震，张庆松，等.速凝浆液裂隙动水注浆扩散规律模拟试验[J].土木工程学报，2017,50(1):86-94.LIU R, ZHANG L, ZHANG Q, et al. Model test on quick setting slurry diffusion law of crack grouting with dynamic water[J]. China Civil Engineering Journal,2017,50(1):86-94.
• [54]李术才，张霄，张庆松，等.地下工程涌突水注浆止水浆液扩散机制和封堵方法研究[J].岩石力学与工程学报，2011,30(12):2377-2396.LI S, ZHANG X, ZHANG Q, et al. Research on mechanism of grout diffusion of dynamic grouting and plugging method in water inrush of underground engineering[J]. Chinese Journal of Rock Mechanics and Engineering,2011,30(12):2377-2396.
• [55]刘人太，李术才，张庆松，等.一种新型动水注浆材料的试验与应用研究[J].岩石力学与工程学报，2011,30(7):1454-1459.LIU R, LI S, ZHANG Q, et al. Experiment and application research on a new type of dynamic water grouting material[J]. Chinese Journal of Rock Mechanics and Engineering,2011,30(7):1454-1459.
• [56]张庆松，王洪波，刘人太，等.考虑浆液扩散路径的多孔介质渗透注浆机理研究[J].岩土工程学报，2018,40(5):918-924.ZHANG Q, WANG H, LIU R, et al. Porous media seepage grouting mechanism research basing on grout diffusion path[J]. Chinese Journal of Geotechnical Engineering,2018,40(5):918-924.
• [57]张庆松，张连震，刘人太，等.水泥-水玻璃浆液裂隙注浆扩散的室内试验研究[J].岩土力学，2015(8):2159-2168.ZHANG Q, ZHANG L, LIU R, et al. Laboratory experimental study of cement-silicate slurry diffusion law of crack grouting with dynamic water[J]. Rock and Soil Mechanics,2015(8):2159-2168.
• [58]董浩.基于浆液性能控制的岩溶裂隙注浆扩散规律及应用研究[D].北京：北京交通大学，2017.DONG H. Study on diffusion law and application of Karst fracture grouting based on grout performance control[D]. Beijing:Beijing Jiaotong University, 2017.
• [59]李昂，李远谋，姬亚东，等.煤矿多孔骨料注浆截流试验机理研究[J].煤炭科学技术，2024(S2):153-161.LI A, LI Y, JI Y, et al. Research on the experimental mechanism of grouting and interception of porous[J]. Coal Science and Technology,2024(S2):153-161.
• [60]乔卫国，张玉侠，宋晓辉，等.水泥浆液在岩体裂隙中的流动沉积机理[J].岩土力学，2004(S1):14-16.QIAO W, ZHANG Y, SONG X, et al. Flow deposition mechanism of cement slurry in rock ass fractures[J]. Rock and Soil Mechanics,2004(S1):14-16.
• [61]沙飞，李术才，林春金，等.砂土介质注浆渗透扩散试验与加固机制研究[J].岩土力学，2019,40(11):4259-4269.SHA Fei, LI Shucai, LIN Chunjin, et al. Research on penetration grouting diffusion experiment and reinforcement mechanism for sandy soil porous media[J]. Rock and Soil Mechanics,2019,40(11):4259-4269.
• [62]ZAITSEV Y B, WITTMANN F H.Simulation of crack propagation and failure of concrete[J].Matériaux et Construction,1981,14(5):357-365.
• [63]李志鹏，张连震，张庆松，等.砂层渗透注浆加固效果模型试验研究[J].煤炭学报，2018,43(12):3488-3497.LI Z, ZHANG L, ZHANG Q, et al. Simulation test for permeation grouting reinforcement effect of sand layer[J]. Journal of China Coal Society,2018,43(12):3488-3497.
• [64]李召峰，李术才，刘人太，等.富水破碎岩体注浆加固实验与机制研究[J].岩石力学与工程学报，2017,36(1):198-207.LI Z, LI S, LIU R, et al. Grouting reinforcement experiment for waterrich broken rock mass[J]. Chinese Journal of Rock Mechanics and Engineering, 2017,36(1):198-207.
• [65]何富连，杨增强，魏臻.采动影响下碎裂煤巷注浆加固优化研究与应用[J].煤矿开采，2017,22(1):50-54,72.HE F, YANG Z, WEI Z. Optimal studying of grouting reinforcement of broken coal roadway under mining influence[J]. Coal Mining Technology, 2017,22(1):50-54,72.
• [66]金煜皓.裂隙泥岩渗透注浆浆液失水效应与扩散特性研究[D].江苏徐州：中国矿业大学，2020.JIN Y. Study on the water loss effect and diffusion characteristics of grout in seepage grouting of fractured mudstone[D]. Xuzhou,Jiangsu:China Universtiy of Mining and Technology, 2020.
• [67]李训魁，杜铭辛，赵向东，等.速效水泥混合浆液注浆技术在强涌水复杂地层中的应用[J].中国煤炭地质，2021,33(10):100-111.LI X, DU M, ZHAO X, et al. Application of accelerated cement mixed slurry grouting technology in strong water gushing complex strata[J].Coal Geology of China, 2021, 33(10):100-111.
• [68]王海.动水条件下煤矿岩体裂隙与管道注浆新型材料性能试验研究[J].中国煤炭地质，2024,36(1):48-52,17.WANG H. Experimental study on the performance of new materials for coal mine rock mass fractures and pipeline grouting under dynamic water conditions[J]. Coal Geology of China, 2024,36(1):48-52,17.
• [69]王树营，吴铁卫，高磊.近煤薄层灰岩水文地质特征及其在超前区域治理中的作用[J].中国煤炭地质，2024,36(11):43-46,36.WANG S, WU T, GAO L. Hydrogeological characteristics of thin limestone near coal and its role in advanced regional governance[J].Coal Geology of China, 2024,36(11):43-46,36.
• [70]许宏发，耿汉生，李朝甫，等.破碎岩体注浆加固体强度估计[J].岩土工程学报，2013,35(11):2018-2022.XU H, GENG H, LI C, et al. Estimating strength of grouting reinforced bodies in broken rock mass[J]. Chinese Journal of Geotechnical Engineering, 2013, 35(11):2018-2022.
• [71]杜跃.碳纳米管水泥基注浆材料加固破碎岩石机理的研究[D].江苏徐州：中国矿业大学，2021.DU Y. Research on the mechanism of carbon nanotube cement-based grouting material to strengthen broken rock[D]. Xuzhou,Jiangsu:China Universtiy of Mining and Technology, 2021.
• [72]金珊珊，杨金龙，索智，等.基于分形理论的水泥砂浆强度预测模型[J].混凝土与水泥制品，2020,290(6):1-5,12.JIN S, YANG J, SUO Z, et al. The strength prediction model of cement mortar based on fractal theory[J]. China Concrete and Cement Products, 2020,290(6):1-5,12.
• [73]姜鹏，章剑青，方磊.基于Archie理论的水泥土强度增长模型[J].公路，2019,64(10):74-78.JIANG P, ZHANG J, FANG L. Strength growth model of cement soil based on Archie theory[J]. Highway,2019,64(10):74-78.
• [74]潘旭东，李鸿钊，郭焱旭，等.海洋环境下注浆加固体的力学性能演化[J].山东大学学报（工学版），2023,53(1):1-9.PAN X, LI H, GUO Y, et al. Mechanical properties of grouting reinforced body under seawater[J]. Journal of Shandong University(Engineering Science),2023,53(1):1-9.
• [75]张涛麟，耿汉生，许宏发，等.钙质砂注浆加固材料制备及固结体性能试验研究[J].岩土力学，2022,43(S2):327-336.ZHANG T, GENG H, XU H, et al. Experimental study on calcareous sand grout material preparation and performance of consolidated solids[J]. Rock and Soil Mechanics,2022,43(S2):327-336.
• [76]易富，姜旭桐，李军，等.离子侵蚀下注浆结石体劣化机理分析[J].水文地质工程地质，2022,49(6):200-208.YI F, JIANG X, LI J, et al. An analysis of the deterioration mechanism of a grouting stone under the ion erosion[J]. Hydrogeology and Engineering Geology,2022,49(6):200-208.
• [77]周茗如，曹润倬，周群，等.采用响应曲面优化法优化水泥基注浆材料的强度与耐硫酸盐腐蚀的试验研究[J].建筑科学，2019,35(1):101-107.ZHOU M, CAO R, ZHOU Q, et al. Test research on optimizing the strength of cement based grouting material with response surface optimization and sulfate resistance[J]. Building Science,2019,35(1):101-107.
• [78]涂鹏.注浆结石体耐久性试验及评估理论研究[D].湖南长沙：中南大学，2012.TU P. Durability experiment and evaluation theory of grouting concretion stone[D]. Changsha,Hunan:Central South University,2012.