煤系锂资源赋存与提取利用研究进展Research Progress on the Occurrence, Extraction and Utilization of Lithium Resources in Coal
田啸,孙杰,严晓云,程路路,邸少波,张莉,韩立强,靳祥成,王志鹏
摘要(Abstract):
锂作为新能源电池等领域应用广泛,战略价值重大。我国锂资源以卤水型为主,提取难度大、开发条件差,亟须新型锂资源,煤系锂资源的发现为此提供了新方向。煤中锂主要赋存于高岭石等黏土矿物,煤灰中锂赋存在玻璃相。研究其赋存状态的方法包括逐级化学提取、数理统计分析等间接法,以及TOF-SIMS、LA-ICP-MS等直接法。煤系锂提取以酸浸为主,因矿物耐酸性常需预处理,预活化-酸浸法(机械、焙烧活化)可提升浸出率,有机酸(如草酸)浸出为绿色提锂提供思路。分离提纯多采用溶剂萃取、沉淀、吸附法,但煤基体系应用研究较少。目前,煤系锂提取面临强酸污染、能耗高、分离技术适应性差等问题。未来需深入研究绿色提取技术、优化工艺降能耗,实现高效环保利用。
关键词(KeyWords): 煤;锂;赋存状态;提取
基金项目(Foundation): 国家重点研发计划资助项目(2023YFC2906404);; 中国煤炭地质总局勘查研究总院青年基金项目“AI+地质大数据找矿模型研究”(ZYQJ-2025-10);; 国家自然科学基金资助项目(42472242)
作者(Author): 田啸,孙杰,严晓云,程路路,邸少波,张莉,韩立强,靳祥成,王志鹏
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