杨兴科,宋洪柱,吕大炜,王东东,钟敦河

• 1:山东科技大学地球科学与工程学院
• 2:中煤一局集团有限公司

摘要(Abstract)：

天然氢作为零碳排放的清洁能源，其研究对推动能源转型和实现“碳中和”具有重大意义。对天然氢的成因机制、控制因素与分布规律进行了系统研究。结果表明：天然氢的成因机制复杂，主要包括无机成因（如水岩反应、深源地幔脱气、地壳水的辐射裂解）和有机成因（如有机质热解与裂解、微生物作用）。天然氢的富集受断裂带、克拉通盆地、岩石类型、地球化学特征等多因素协同控制，赋存形式多样，包括游离态、溶解态和吸附态；天然氢资源在全球范围内分布广泛，国内天然氢的富集区主要集中分布在阿尔金断裂带及两侧盆地区、三江构造带、龙门山断裂带及周缘盆地区、郯庐断裂带及周缘裂陷盆地区。本研究厘清了天然氢的多成因机制与富集主控因素，为其勘探开发靶区优选提供了理论依据，对推动其在能源转型中的应用具有重要价值。

关键词(KeyWords)： 天然氢;成因机制;控制因素;赋存特征;富集规律;能源转型

Abstract:

Keywords:

基金项目(Foundation): 中央引导地方科技发展资金（YDZX2023056）;; 中煤一局集团有限公司揭榜挂帅项目（ZMYJ-JBGS-2025-02）

作者(Author): 杨兴科,宋洪柱,吕大炜,王东东,钟敦河

参考文献(References)：

• [1]ZGONNIK V. The occurrence and geoscience of natural hydrogen:A comprehensive review[J]. Earth-Science Reviews, 2020, 203.
• [2]MILKOV A V. Molecular hydrogen in surface and subsurface natural gases:Abundance, origins and ideas for deliberate exploration[J].Earth-Science Reviews, 2022, 230.
• [3]Science News Staff. Breakthrough of the Year:Natural hydrogen[J]. Science, 2023, 382(6676):1228-1231.
• [4]McKinsey&Company. Global energy perspective 2023:Hydrogen outlook[EB/OL].(2024-01-10)[2024-06-07]. https：//www.mckinsey. com/industries/oil-and-gas/our-insights/global-energyperspective-2023-hydrogen-outlook.
• [5]BALLENTINE J C, KAROLYT??R, CHENG A, et al. Natural hydrogen resource accumulation in the continental crust[J]. Nature Reviews Earth&Environment, 2025, 6(5):342-356.
• [6]CHOQUETTE P S, CONSTANT P. Molecular Hydrogen, a Neglected key driver of soil biogeochemical processes[J]. Applied and Environmental Microbiology, 2019, 85(6):e02418-18.
• [7]宇波，李敬法，田坤，等.天然氢勘探开发与集输研究现状及展望[J].油气储运，2025,44(3):241-260.
• [8]COVENEY R M, GOEBEL E D, ZELLER E J, et al.Serpentinization and the origin of hydrogen gas in Kansas[J]. AAPG Bulletin, 1987, 71(1):39-48.
• [9]ETIOPE G, SCHOELL M, HOSG??RMEZ H. Abiotic methane flux from the Chimaera seep and Tekirova ophiolites(Turkey):understanding gas exhalation from low temperature serpentinization and implications for Mars. Earth and Planetary Science Letters, 2011, 310(1-2), 96-104.
• [10]NEUBECK A, DUC N T, BASTVIKEN D, et al. Formation of H2and CH4 by weathering of olivine at temperatures between 30℃and70℃. Geochemical Transactions, 2011, 12:1-10.
• [11]KLEIN F, BACH W, J??NS N, et al. Iron partitioning and hydrogen generation during serpentinization of abyssal peridotites from15N on the Mid-Atlantic Ridge[J]. Geochimica et Cosmochimica Acta,2009, 73(22):6868-6893.
• [12]章钰桢，姜兆霞，李三忠，等.大洋橄榄岩的蛇纹石化过程：从海底水化到俯冲脱水[J].岩石学报，2022,38(4):1063-1080.
• [13]MCCOLLOM, THOMAS M, FRIEDER K, et al. Hydrogen generation from serpentinization of iron-rich olivine on Mars, icy moons, and other planetary bodies[J]. Icarus, 2022, 372.
• [14]WILLIAMS Q,HEMLEY R J, et al. Hydrogen in the deep earth[J]. Annual Review of Earth and Planetary Sciences, 2001, 29(1):365-418.
• [15]SCHMANDT B, JACOBSEN S D, BECKER T W, et al.Dehydration melting at the top of the lower mantle[J]. Science, 2014,344(6189):1265-1268.
• [16]CRUIKSHANK D P, MORRISON D, LENNON K. Volcanic gases:hydrogen burning at Kilauea Volcano, Hawaii[J]. Science,1973, 182(4109):277-279.
• [17]STALKER L, TALUKDER A, STRAND J, et al. Gold(hydrogen)rush:risks and uncertainties in exploring for naturally occurring hydrogen[J]. The APPEA Journal, 2022, 62(1):361-380.
• [18]DAS D, VEZIROGLU N T. Advances in biological hydrogen production processes[J]. International Journal of Hydrogen Energy,2008, 33(21):6046-6057.
• [19]AMILS R, ESCUDERO C, OGGERIN M, et al. S and Fe biogeochemical cycles operating in the continental deep subsurface of the Iberian Pyrite Belt. Environmental Microbiology, 2023, 25(2),428-453.
• [20]王晓锋，刘文汇，徐永昌，等.水介质对气态烃形成演化过程氢同位素组成的影响[J].中国科学：地球科学，2012,42(1):103-110.
• [21]钟宁宁，等.显微组分激光诱导荧光特性与其富氢程度关系的初步研究[J].科学通报，2000,45(3):323-328.
• [22]LEWAN M D. Experiments on the role of water in petroleum formation. Geochim Cosmochim Acta, 1997, 61:3691-3723.
• [23]MCCOLLOM, THOMAS M, KLEIN F, et al. Hydrogen generation and iron partitioning during experimental serpentinization of an olivine-pyroxene mixture[J]. Geochimica et Cosmochimica Acta,2020, 282:55-75.
• [24]LOLLAR B S, ONSTOTT T C, LACRAMPE-COULOUME G, et al. The contribution of the Precambrian continental lithosphere to global H2 production[J]. Nature, 2014, 516(7531):379-382.
• [25]SHERWOOD L B, VOGLESONGER K, LIN L H, et al.Hydrogeologic controls on episodic H2 release from precambrian fractured rocks-energy for deep subsurface life on earth and mars[J].Astrobiology, 2007, 7(6):971-986.
• [26]于志琪，刘汇川，朱光有，等.基于蛇纹石化生氢影响因素的制氢方式新思考[J].天然气工业，2023,43(8):156-169.
• [27]ALLEN D E, SEYFRIED W E. Compositional controls on vent fluids from ultramatic-hosted hydrothermal systems at mid-ocean ridges:An experimental study at 400℃，500 bars[J]. Geochimica et Cosmochimica Acta:Journal of the Geochemical Society and the Meteoritical Society, 2003, 67(8):1531-1542.
• [28]HU G, HOU J, ZHU Z, et al. Genetic mechanism and exploration progress of global deep alkane gases and small molecule gases(H2, He)[J]. Gas Science and Engineering, 2024, 131.
• [29]GAUCHER C E. New Perspectives in the Industrial Exploration for Native Hydrogen[J]. Elements, 2020, 16(1):8-9.
• [30]PRINZHOFER A, CISS??S C, DIALLO B A, et al. Discovery of a large accumulation of natural hydrogen in Bourakebougou(Mali)[J].International Journal of Hydrogen Energy, 2018, 43(42):19315-19326.
• [31]LAMADRID H M, RIMSTIDTI J, DONALD et al. Effect of water activity on rates of serpentinization of olivine[J]. Nature Communications, 2017, 8(1).
• [32]李永豪，曹剑，胡文瑄，等.膏盐岩油气封盖性研究进展[J].石油与天然气地质，2016,37(5):634-643.
• [33]KLEIN F, GROZEVA N, SEEWALD J. Abiotic methane synthesis and serpentinization in olivine-hosted fluid inclusions[J]. Proceedings of the National Academy of Sciences, 2019, 116(36):17666-17672.
• [34]MCCOLLOM M T, KLEIN F, ROBBINS M, et al. Temperature trends for reaction rates, hydrogen generation, and partitioning of iron during experimental serpentinization of olivine[J]. Geochimica et Cosmochimica Acta, 2016, 181:175-200.
• [35]TRUCHE L, DONZ??V F, GOSKOLLI E, et al. A deep reservoir for hydrogen drives intense degassing in the Bulqiz??ophiolite[J].Science, 2024, 383(6683):618-621.
• [36]GU??LARD J, BEAUMONT V, ROUCHON V, et al. Natural H2 in Kansas:Deep or shallow origin?[J]. Geochemistry, Geophysics,Geosystems, 2017, 18(5):1841-1865.
• [37]高金亮，刘嘉麒，郭正府，等.双辽新生代玄武岩及地幔捕虏体内流体的组成、碳同位素特征及其来源[J].岩石学报，2017,33(1):81-92.
• [38]王先彬，徐胜，陈践发，等.腾冲火山区温泉气体组分和氦同位素组成特征[J].科学通报，1993,38(9):814-817.
• [39]上官志冠，白春华，孙明良.腾冲热海地区现代幔源岩浆气体释放特征[J].中国科学（D辑：地球科学），2000,30(4):407-414.
• [40]高清武.长白山天池火山水热活动及气体释放特征[J].地球学报，2004,25(3):345-350.
• [41]LIU Q, JIN Z, MENG Q, et al. Genetic types of natural gas and filling patterns in Daniudi gas field, Ordos Basin, China[J]. Journal of Asian Earth Sciences, 2015, 107:1-11.
• [42]金之钧，张刘平，杨雷，等.沉积盆地深部流体的地球化学特征及油气成藏效应初探[J].地球科学，2002,27(6):659-665.
• [43]朱光，刘程，顾承串，等.郯庐断裂带晚中生代演化对西太平洋俯冲历史的指示[J].中国科学：地球科学，2018,48(4):415-435.
• [44]张水昌，朱光有，陈建平，等.四川盆地川东北部飞仙关组高含硫化氢大型气田群气源探讨[J].科学通报，2007, 52(S1):86-94.
• [45]徐义刚，何斌，罗震宇，等.我国大火成岩省和地幔柱研究进展与展望[J].矿物岩石地球化学通报，2013,32(1):25-39.
• [46]窦立荣，刘化清，李博，等.全球天然氢气勘探开发利用进展及中国的勘探前景[J].岩性油气藏，2024,36(2):1-14.
• [47]LIU Q, ZHU D, JIN Z, et al. Effects of deep CO2 on petroleum and thermal alteration:the case of the Huangqiao oil and gas field[J].Chemical Geology, 2017, 469:214-229.
• [48]WANG L, LIU Q, LIU K, et al. The occurrence pattern of natural hydrogen in the Songliao Basin, PR China:Insights on natural hydrogen exploration[J]. International Journal of Hydrogen Energy,2024, 2(50):261-75.
• [49]CHEN X, LI Z, CHEN J, et al. Determination of the reverse period of Songliao Basin, China[J]. Geological Bulletin of China,2010:29(2/3):305-311.
• [50]刘培，蒋有录，刘华，等.渤海湾盆地沾化凹陷断层活动与新近系油气成藏关系[J].天然气地球科学，2013,24(3):541-547.
• [51]MENG Q, SUN Y,TONG J, et al. Distribution and geochemical characteristics of hydrogen in natural gas from the Jiyang depression,Eastern China[J]. Acta Geologica Sinica(English Edition), 2015, 89(5):1616-1624.
• [52]孟庆强.地质体中天然氢气成因识别方法初探[J].石油实验地质，2022,44(3):552-558.
• [53]余川，包书景，秦启荣，等.川东南地区下志留统页岩气成藏条件分析[J].石油天然气学报，2012,34(2):5.
• [54]秦川，余谦，刘伟，等.黔北地区牛蹄塘组富有机质泥岩储层特征[J].西南石油大学学报（自然科学版），2017,39(4):13-24.
• [55]郑金云，高阳东，张向涛，等.珠江口盆地构造演化旋回及其新生代沉积环境变迁[J].地球科学，2022,47(7):2374-2390.
• [56]赵冬，丁文龙，刘建军，等.沁水盆地煤系天然气系统富集成藏的主控因素分析[J].科学技术与工程，2015,15(22):137-147.
• [57]周强，江洪清，梁汉东.沁水盆地南部煤层气中氢气释放规律研究[J].天然气地球科学，2006, 17(6):871-873.
• [58]ELLIS G, GELMAN S E. A preliminary model of global subsurface natural hydrogen resource potential[C]//Geological Society of America Annual Meeting Abstracts. 2022, 54(5):380.
• [59]POTTER J, RANKIN H A, TRELOAR J P, et al. Abiogenic Fischer–Tropsch synthesis of hydrocarbons in alkaline igneous rocks;fluid inclusion, textural and isotopic evidence from the Lovozero complex, N.W. Russia[J]. Lithos, 2004, 75(3-4):311-330.
• [60]KAWKES H. Geothermal hydrogen[J]. Mining Engineering,1980:671-675.
• [61]MAIGA O, DEVILLE E, LAVAL J, et al. Trap processes of large volumes of natural hydrogen in the subsurface:The emblematic case of the Bourakebougou H2 field in Mali[J]. International Journal of Hydrogen Energy, 2024, 2(50):640-647.