巴西巴拉纳(Parana)盆地下二叠统伊拉蒂组(Irati)油页岩地球化学特征及地质意义Lower Permian Irati Formation Oil Shale Geochemical Features and Geological Significance in Parana Basin, Brazil
于婷婷,刘招君,王君贤,孟庆涛,李元吉
摘要(Abstract):
巴西巴拉纳(Parana)盆地是南美洲重要的含油气盆地,除了丰富的石油资源外,其所蕴藏的浅层可商业开采的油页岩资源也备受瞩目。目前,对巴拉纳盆地下二叠统伊拉蒂组油页岩的研究多集中在工业利用等方面,对其地球化学特征和油页岩形成条件等方面研究甚少,且尚无国内一手研究结果。通过对露天矿油页岩样品进行了总有机碳含量(TOC)、岩石热解、生物标志化合物、有机显微组分鉴定、主微量元素测定、全岩及黏土X衍射和工业分析等方面的测试,分析了巴拉纳盆地油页岩地球化学特征,并对有机质来源和沉积环境进行判别。结果显示,巴拉纳盆地油页岩具有较高的有机质丰度,TOC(质量分数)可达23.2%,有机质类型为I型,有机质来源以藻类体为主,辅以陆源高等植物;正构烷烃呈低碳数为主的单峰型分布;规则甾烷相对含量呈C_(29)>C_(27)>C_(28);沉积地球化学环境敏感参数显示,伊拉蒂组油页岩沉积时期CIA为72,整体上呈温暖湿润的气候背景,温湿气候背景下伴随着较高的生物生产力,同时缺氧的水体环境有利于有机质的保存,促进了伊拉蒂组优质油页岩的形成。
关键词(KeyWords): 巴拉纳盆地;伊拉蒂组;油页岩;地球化学特征;古沉积环境
基金项目(Foundation):
作者(Author): 于婷婷,刘招君,王君贤,孟庆涛,李元吉
参考文献(References):
- [1]刘招君,杨虎林,董清水,等.中国油页岩[M].北京:石油工业出版社,2009.
- [2]邹才能,杨智,朱如凯,等.中国非常规油气勘探开发与理论技术进展[J].地质学报,2015,89(6):979-1007.
- [3]Hill G A,Affholter J A.Integrated in situ retorting and refining of oil shale[P].U S,2012.
- [4]Liu Z,Meng Q,Dong Q,et al.Characteristics and resource potential of oil shale in China[J].Oil Shale,2017,34(1):15-41.
- [5]Bai Y,Liu Z,Sun P,et al.Diverse sedimentary conditions during deposition of coal and oil shale from the Meihe Basin(Eocene,NE China)[J].Journal of Sedimentary Research,2017,87(10):1100-1120.
- [6]Li L,Liu Z,George S C,et al.Lake evolution and its influence on the formation of oil shales in the Middle Jurassic Shimengou Formation in the Tuanyushan area,Qaidam Basin,NW China[J].Geochemistry,2019,79(1):162-177.
- [7]Wang J X,Sun P C,Liu Z J,et al.Evaluation of oil shale resources based on geochemistry and logging in Tuanyushan,Qaidam Basin,Northwest China[J].Oil Shale,2020,37(3):188-206.
- [8]Zalán P V,Wolff S,Marco A M,et al.The Parana Basin,Brazil:Chapter 33:Part II.Selected Analog Interior Cratonic Basins:Analog Basins[J].AAPG Special Volumes,1990,A134:681-708.
- [9]Darlly E S,Rodrigues R,Moldowan J M,et al.Biomarkers stratigraphy of Irati Formation (lower permian) in the southernportion of Paraná Basin (Brazil)[J].Marine and Petroleum Geology,2018,95:110-138.
- [10]柳蓉,刘招君.国内外油页岩资源现状及综合开发潜力分析[J].吉林大学学报,2006,36(6):893-897.
- [11]Jackson L L,Roof S R.Determination of the forms of carbon in geologic materials[J].Geostandards and Geoanalytical Research,1992,16(2):317-323.
- [12]Lafargue E,Marquis F,Pillot D.Rock-Eval 6 Applications in Hydrocarbon Exploration,Production,and Soil Contamination Studies[J].Oil & Gas Science & Technology,1998 ,53(4):421-437.
- [13]Didyk B M,Simoneit B R T,Brassell S C,et al.Organic geochemical indicators of palaeoenvironmental conditions of sedimentation[J].Nature,1978,272:216-222.
- [14]Peters K E,Peters K E,Walters C C,et al.The biomarker guide[M].Cambridge University Press,2005.
- [15]张立平,黄第藩,廖志勤.伽马蜡烷—水体分层的地球化学标志[J].沉积学报,1999,17(1):136-140.
- [16]Fedo C M,Nesbtit H W,Young G M.Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols,with implications for paleo weathering conditions and provenance[J].Geology,1995,23(10):921-924.
- [17]Langford F.Interpreting Rock-Eval pyrolysis data using graphs of pyrolizable hydrocarbons vs.Toal Organic Carbon[J].AAPG Bulletin,1990,74(6):799-804.
- [18]Mukhopadayay P K,Wade J A,Kruge M A.Organic facies and maturation of Jurassic/Cretaceous rocks,and possible oil-source rock correlation based on pyrolysis of asphaltenes,Scotian Basin,Canada[J].Organic Geochemistry,1995,22(1):85-104.
- [19]Fathy D,Wagreich M,Gier S,et al.Maastrichtian oil shale deposition on the southern Tethys margin,Egypt:Insights into greenhouse climate and paleoceanography[J].Palaeogeography,Palaeoclimatology,Palaeoecology,2018,505:18-32.
- [20]Zeng S,Wang J,Fu X,et al.Geochemical characteristics redox conditions and organic matter accumulation of marine oil shale from the Changliang Mountain area northern Tibet China[J].Marine and Petroleum Geology,2015,64:203-221.
- [21]Murphy A E,Sageman B B,Hollander D J,et al.Black shale deposition and faunal overturn in the Devonian Appalachian Basin:Clastic starvation,seasonal water-column mixing,and efficient biolimiting nutrient recycling[J].Paleoceanography,2000,15(3):280-291.
- [22]Calvert S E,Pedersen T F.Chapter Fourteen Elemental Proxies for Palaeoclimatic and Palaeoceanographic Variability in Marine Sediments:Interpretation and Application[J].Developments in Marine Geology,2007(1):567-644.
- [23]Schmitz B.The TiO2/Al2O3 ratio in the Cenozoic Bengal Abyssal Fan sediments and its use as a paleostream energy indicator[J].Marine Geology,1987,76:195-206.
- [24]Tian J,Xie X,Ma W,et al.X-ray fluorescence core scanning records of chemical weathering and monsoon evolution over the past 5 Myr in the southern South China Sea[J].Paleoceanography,2011,26:1-17.
- [25]Rieu R,Allen P A,Pl?tze M,et al.Climatic cycles during a Neoproterozoic “snowball” glacial epoch[J].Geology,2007,35(4):299-302.
- [26]Cao J,Wu M,Chan Y,et al.Trace and rare earth elements geochemistry of Jurassic mudstones in the northern Qaidam basin,northwest China[J].Geochemistry,2012,72(3):245-252.
- [27]Moradi A V,Sar? A,Akkaya P.Geochemistry of the miocene oil shale (han?li formation) in the ?nk?r?-?rum basin,central Turkey:implications for paleoclimate conditions,source–area weathering,provenance and tectonic setting[J].Sedimentary Geology,2016,341:289-303.
- [28]He C,Ji L M,Su A,et al.Source-rockevaluation and depositional environment of black shales in the Triassic Yanchang Formation,southern Ordos Basin,north-central China[J].Journal of Petroleum Science and Engineering,2019,173:899-911.